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21.
Teresa uczak Radosaw Pankiewicz Bogusawa ska Grzegorz Schroeder Maria Betowska-Brzezinska Bogumil Brzezinski 《Journal of Molecular Structure》2006,800(1-3):140-145
Novel self-assembled monolayers were obtained on silver using 4,7-diazaheptyl-trimethoxy-silane (SiN) and vinyl-trialkoxy-silane (SiVA, where the alkyl group is 3,6,9,12,15,18,21,24,27,30,33,36,39,42,45,48,51,54,57,60-eicozaoxa- hexaheptaconan). It was shown that thus modified metal surface was protected against electrooxidation. A densely packed monolayer remained stable and did not desorb from the Ag electrode on the potential cycling. The structure of SiN and SiVA as well as their complexes with Li+ cations were calculated and visualised by the AM1d and PM5 semi-empirical methods. 相似文献
22.
1 INTRODUCTION The self-assembly of organic-inorganic hybrid ma- terials is an intriguing area, which is yielding new generations of supramolecular architectures[1, 2]. Coor- dination by transition metals with multifunctional ligands is one of the main design principles. As a rigid multi-dentate ligand, 5-aminoisophthalic acid (AIP) has received considerable attention owing to the variety of bridging abilities[3~8]. It can engage in three types of intermolecular interactions: (1) M-L b… 相似文献
23.
Ya. I. Kurys’ N. S. Netyaga V. G. Koshechko V. D. Pokhodenko 《Theoretical and Experimental Chemistry》2007,43(5):334-342
A guest-host nanocomposite based on electroconducting polyaniline doped with 12-phosphotungstic acid and V2O5 as well as its bifunctional analog containing not more than 5 mass% nanosized platinum were obtained. A study was carried
out on the structure of these nanocomposites, their redox characteristics, and electrocatalytic activity in the reduction
of oxygen. These nanocomposites were found to display catalytic properties in the electrochemical reduction of oxygen, while
the presence of even a slight amount of nanosized platinum in the bifunctional composite leads to a significant increase in
its electrocatalytic activity.
__________
Translated from Teoreticheskaya i éksperimental’naya Khimiya, Vol. 43, No. 5, pp. 307–314, September–October, 2007. 相似文献
24.
The effect of bacterial and fungal activities on organic matter degradation in Brazilian soils was studied by a microcalorimetric method. Bacteria and fungi isolated from tropical soils and added to: Rhodic eutrudox (R), Typic eutrudox (V) and Quartzipsamment (Q) soils amended separately with moisture (control) (A) and 25% of cattle manure (E), municipal refuse compost (L), earthworm casts (H) or 23 μg of trifluralin (T) were investigated. The number of colony forming units in soil suspension was quantified by microscopy and inoculated in respective soil. All processes were measured at intervals of 7 days over a period of 35 days. The exothermic thermal effect (μJ) per cm3 of bacteria or fungi per gram of dry soil, respectively, for each substrate was: [(9±1), (4±1)] RA; [(478±24), (105±5)] RE; [(121±6), (71±4)] RL; [(121±6), (71±4)] RH; [(8±1); (3±1)] RT; [(10±1), (9±1] VA; [(347±17), (261±13)] VE; [(71±4), (28±1)] VL; [(22±1), (33±2)] VH; [(7±1), (10±1)] VT; [(19±1), (12±1)] QA; [(1301±65), (46±2)] QE; [(89±4), (9±1)] QL; [(130±7), (11±1)] QH; [(32±2), (8±1)] QT. The calorimetric values are higher for bacteria than for fungi. In general, the results showed higher activities in the soil amended with cattle manure than with other additives. 相似文献
25.
Data on methods for the production of isatin and indole aldoximes, ketoximes, and amidoximes and their reactions are reviewed. Individual syntheses of new heterocycles from indole and isatin oximes are discussed. The principal results from investigation of the biological activity of derivatives of the oximes are also presented. 相似文献
26.
Miho Katoh 《Tetrahedron letters》2004,45(33):6221-6223
A novel and stereocontrolled synthetic path to a potential antimalarial piperidine alkaloid, (+)-febrifugine, was established by employing the reductive deamination and simultaneous recyclization of a proline derivative with samarium diiodide, as a key step. 相似文献
27.
Milan V. Patel Samir A. Patel Arabinda Ray Rajni M. Patel 《Journal of polymer science. Part A, Polymer chemistry》2004,42(20):5227-5234
Copolymers of monomers 2,4‐dichlorophenyl methacrylate (2,4‐DMA) and methyl methacrylate (MMA) were synthesized with different monomer feed ratios using toluene as a solvent and 2,2′‐azobisisobutyronitrile (AIBN) as an initiator at 70 °C. The copolymers were characterized by IR‐spectroscopy, and copolymer composition was determined with UV‐spectroscopy. The linearization method of Fineman–Ross was employed to obtain the monomer reactivity ratios. The molecular weights and polydispersity indexes were determined by gel permeation chromatography (GPC). Thermogravimetric analyses of polymers were carried out in nitrogen atmosphere. The homo‐ and copolymers were tested for their antimicrobial properties against selected microorganisms. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 5227–5234, 2004 相似文献
28.
Ibrahim Erol 《Journal of polymer science. Part A, Polymer chemistry》2004,42(13):3157-3169
A new type of methacrylate monomer, [2‐oxo‐2‐(4‐acetyl) phenyl amino] ethylene methacrylate (APEMA), was synthesized. The oxime, 2,4‐dinitrophenylhydrazone, and thiosemicarbazone derivatives of poly{[2‐oxo‐2‐(4‐acetyl) phenyl amino] ethylene methacrylate} [poly(APEMA)] were prepared with hydroxylamine hydrochloride, 2,4‐dinitrophenylhydrazine, and thiosemicarbazone hydrochloride, respectively. The radical homopolymerization of APEMA was performed at 65 °C in a 1,4‐dioxane solution with benzoyl peroxide as an initiator. The monomer and its homopolymer were characterized with Fourier transform infrared and NMR techniques. The thermal stabilities of poly(APEMA) and its derivatives were investigated with thermogravimetric analysis and differential scanning calorimetry. The ultraviolet stability of the polymers were compared. The solubility and inherent viscosity of the polymers were also determined. The number‐average and weight‐average molecular weights and polydispersity index of the polymers were determined with gel permeation chromatography. The antibacterial and antifungal effects of the monomer and the polymer and its derivatives were also investigated on various bacteria and fungi. The activation energies of the thermal degradation of the polymers were calculated with the Ozawa method. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 3157–3169, 2004 相似文献
29.
30.
报道了新合成的二氰基二硫纶·菲咯啉-5,6-二酮合铜(Ⅱ)配合物CuLL′(L=mnt2-, 1,2-dicyano-1,2-ethylenedithiolate; L′=phen-5,6-dione, 1,10-phenanthroline-5,6-dione)的变温磁化率和电子顺磁共振波谱表征结果. 发现微晶粉体型的标题配合物CuLL′具有一定的顺磁性,形成四配位的近似于方形的结构. 探讨了这种配合物磁学特性与结构的关系. 相似文献